5,5'-联四唑
5,5'-联四唑是一种有机化合物,化学式为C2H2N8。它可由氰和叠氮化钠在三氯化铝存在下反应制得,[1]或由5,5'-联四唑二钠和盐酸反应得到。[2]它和过一硫酸钾、乙酸钾反应,可以得到二羟基联四唑。[3]
5,5'-联四唑 | |
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识别 | |
CAS号 | 2783-98-4 |
PubChem | 137711 |
SMILES |
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性质 | |
化学式 | C2H2N8 |
摩尔质量 | 138.09 g·mol−1 |
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。 |
参考文献
编辑- ^ Turnbull, K., Narsaiah, B., Yadav, J. S., Yakaiah, T., & Lingaiah, B. P. V. (2008). Sodium Azide. Encyclopedia of Reagents for Organic Synthesis. doi:10.1002/047084289x.rs045.pub2
- ^ Eulgem, Patrick J.; Klein, Axel; Maggiarosa, Nicola; Naumann, Dieter; Pohl, Roland W. H. New Rare Earth Metal Complexes with Nitrogen‐Rich Ligands: 5,5′‐Bitetrazolate and 1,3‐Bis(tetrazol‐5‐yl)triazenate—On the Borderline between Coordination and the Formation of Salt‐Like Compounds. Chemistry – A European Journal. 2008-04-18, 14 (12): 3727–3736. ISSN 0947-6539. doi:10.1002/chem.200702006.}
- ^ Fischer, Niko; Gao, Li; Klapötke, Thomas M.; Stierstorfer, Jörg. Energetic salts of 5,5′-bis(tetrazole-2-oxide) in a comparison to 5,5′-bis(tetrazole-1-oxide) derivatives. Polyhedron. 2013, 51: 201–210. doi:10.1016/j.poly.2012.12.015.