1,2,3,4,5,6,7,8-八氫萘
1,2,3,4,5,6,7,8-八氫萘是一種有機化合物,化學式為C10H16。它可由四氫萘和鋰在乙二胺溶液中反應得到。[2]4a,8a-八氫萘二酚和鉀、三氯化鈦在四氫呋喃中反應,也能得到該化合物。[3]它可以被過氧化氫氧化為八氫-4a,8a-環氧萘[4]或被高碘酸鈉氧化為1,6-環癸二酮。[5]
1,2,3,4,5,6,7,8-八氫萘 | |
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識別 | |
CAS號 | 493-03-8 ![]() |
SMILES |
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性質 | |
化學式 | C10H16 |
摩爾質量 | 136.23 g·mol−1 |
密度 | 0.9170 g·cm−3(20 °C)[1] |
熔點 | −34 °C(239 K)[1] |
沸點 | 194 °C(467 K)(750 torr)[1] |
若非註明,所有數據均出自標準狀態(25 ℃,100 kPa)下。 |
參考文獻
編輯- ^ 1.0 1.1 1.2 Huckel, Walter; Danneel, Rolf; Schwartz, Albert; Gercke, Achim. Stereochemistry of bicyclic ring systems. V. Δ9,10-Octalin. Justus Liebigs Annalen der Chemie, 1929. 474: 121-144. ISSN: 0075-4617.
- ^ Leslie Reggel, R. A. Friedel, Irving Wender. Lithium in Ethylenediamine: A New Reducing System for Organic Compounds 1. The Journal of Organic Chemistry. 1957-08, 22 (8): 891–894 [2021-04-17]. ISSN 0022-3263. doi:10.1021/jo01359a009 (英語).
- ^ Eric Block. John Wiley & Sons, Inc. , 編. Olefin Synthesis by Deoxygenation of Vicinal Diols. Hoboken, NJ, USA: John Wiley & Sons, Inc. 1984-01-18: 457–566 [2021-04-17]. ISBN 9780471264187. doi:10.1002/0471264180.or030.02 (英語).
- ^ Makoto Nakajima, Yuka Sasaki, Hatsue Iwamoto, Shun-ichi Hashimoto. Bipyridine N,N′-Dioxide: A Felicitous Ligand for Methyltrioxorhenium-Catalyzed Epoxidation of Olefins with Hydrogen Peroxide. Tetrahedron Letters. 1998-01, 39 (1-2): 87–88 [2021-04-17]. doi:10.1016/S0040-4039(97)10495-6 (英語).
- ^ Carley L. Chandler, Benjamin List. Catalytic, Asymmetric Transannular Aldolizations: Total Synthesis of (+)-Hirsutene. Journal of the American Chemical Society. 2008-05, 130 (21): 6737–6739 [2021-04-17]. ISSN 0002-7863. doi:10.1021/ja8024164 (英語).