1,2,3,4,5,6,7,8-八氢萘

1,2,3,4,5,6,7,8-八氢萘是一种有机化合物,化学式为C10H16。它可由四氢萘乙二胺溶液中反应得到。[2]4a,8a-八氢萘二酚和三氯化钛四氢呋喃中反应,也能得到该化合物。[3]它可以被过氧化氢氧化为八氢-4a,8a-环氧萘[4]或被高碘酸钠氧化为1,6-环癸二酮。[5]

1,2,3,4,5,6,7,8-八氢萘
识别
CAS号 493-03-8  checkY
SMILES
 
  • C1CCC2=C(C1)CCCC2
性质
化学式 C10H16
摩尔质量 136.23 g·mol−1
密度 0.9170 g·cm−3(20 °C)[1]
熔点 −34 °C(239 K)[1]
沸点 194 °C(467 K)(750 torr)[1]
若非注明,所有数据均出自标准状态(25 ℃,100 kPa)下。

参考文献

编辑
  1. ^ 1.0 1.1 1.2 Huckel, Walter; Danneel, Rolf; Schwartz, Albert; Gercke, Achim. Stereochemistry of bicyclic ring systems. V. Δ9,10-Octalin. Justus Liebigs Annalen der Chemie, 1929. 474: 121-144. ISSN: 0075-4617.
  2. ^ Leslie Reggel, R. A. Friedel, Irving Wender. Lithium in Ethylenediamine: A New Reducing System for Organic Compounds 1. The Journal of Organic Chemistry. 1957-08, 22 (8): 891–894 [2021-04-17]. ISSN 0022-3263. doi:10.1021/jo01359a009 (英语). 
  3. ^ Eric Block. John Wiley & Sons, Inc. , 编. Olefin Synthesis by Deoxygenation of Vicinal Diols. Hoboken, NJ, USA: John Wiley & Sons, Inc. 1984-01-18: 457–566 [2021-04-17]. ISBN 9780471264187. doi:10.1002/0471264180.or030.02 (英语). 
  4. ^ Makoto Nakajima, Yuka Sasaki, Hatsue Iwamoto, Shun-ichi Hashimoto. Bipyridine N,N′-Dioxide: A Felicitous Ligand for Methyltrioxorhenium-Catalyzed Epoxidation of Olefins with Hydrogen Peroxide. Tetrahedron Letters. 1998-01, 39 (1-2): 87–88 [2021-04-17]. doi:10.1016/S0040-4039(97)10495-6 (英语). 
  5. ^ Carley L. Chandler, Benjamin List. Catalytic, Asymmetric Transannular Aldolizations: Total Synthesis of (+)-Hirsutene. Journal of the American Chemical Society. 2008-05, 130 (21): 6737–6739 [2021-04-17]. ISSN 0002-7863. doi:10.1021/ja8024164 (英语).