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热力学
分支
经典热力学
·
统计力学
·
化学热力学
·
平衡热力学
/
非平衡热力学
定律
零
·
一
·
二
·
三
热力学系统
热力学状态
:
状态方程
理想气体
·
真实气体
物态
·
热力学平衡
·
控制体积
·
过程
:
等压过程
·
等容过程
·
等温过程
·
Adiabatic
·
Isentropic
·
Isenthalpic
Quasistatic
·
Polytropic
·
自由膨胀
·
可逆过程
·
不可逆过程
·
Endoreversibility
· 循环:
热机
·
热泵
·
热机效率
热力学性质
Property diagrams
Intensive and extensive properties
·
State function
s
:
Temperature
/
Entropy
(
intro.
) ?
Pressure
/
Volume
?
Chemical potential
/
Particle no.
?(?
Conjugate variables
)
Vapor quality
Reduced properties
·
Process function
s
:
Work
·
Heat
Material properties
比热容
c
=
{\displaystyle c=}
T
{\displaystyle T}
∂
S
{\displaystyle \partial S}
N
{\displaystyle N}
∂
T
{\displaystyle \partial T}
压缩性
β
=
−
{\displaystyle \beta =-}
1
{\displaystyle 1}
∂
V
{\displaystyle \partial V}
V
{\displaystyle V}
∂
p
{\displaystyle \partial p}
热膨胀
α
=
{\displaystyle \alpha =}
1
{\displaystyle 1}
∂
V
{\displaystyle \partial V}
V
{\displaystyle V}
∂
T
{\displaystyle \partial T}
Property database
Equations
Carnot's theorem
Clausius theorem
Fundamental relation
Ideal gas law
Maxwell relations
·
Table of thermodynamic equations
Potentials
Free energy
·
Free entropy
·
Internal energy
U
(
S
,
V
)
{\displaystyle U(S,V)}
Enthalpy
H
(
S
,
p
)
=
U
+
p
V
{\displaystyle H(S,p)=U+pV}
Helmholtz free energy
A
(
T
,
V
)
=
U
−
T
S
{\displaystyle A(T,V)=U-TS}
Gibbs free energy
G
(
T
,
p
)
=
H
−
T
S
{\displaystyle G(T,p)=H-TS}
History and culture
Philosophy
:
Entropy and time
·
Entropy and life
Brownian ratchet
Maxwell's demon
Heat death paradox
Loschmidt's paradox
Synergetics
·
History
:
General
·
Heat
·
Entropy
·
Gas laws
Perpetual motion
Theories
:
Caloric theory
·
Vis viva
Theory of heat
Mechanical equivalent of heat
Motive power
Publications
:"
An Experimental Enquiry Concerning ... Heat
""
On the Equilibrium of Heterogeneous Substances
"
"Reflections on theMotive Power of Fire"
·
Timelines of
:
Thermodynamics
·
Heat engines
·
Art
:
Maxwell's thermodynamic surface
·
Education
:
Entropy as energy dispersal
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